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  <xs:element id="duol_ShareBasedPaymentArrangementEquityInstrumentsOtherThanOptionsNumberOfSharesEligibleToVestAtStockPriceHurdle" abstract="false" name="ShareBasedPaymentArrangementEquityInstrumentsOtherThanOptionsNumberOfSharesEligibleToVestAtStockPriceHurdle" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="xbrli:sharesItemType"/>
  <xs:element id="duol_ShareBasedPaymentArrangementTrancheFourMember" abstract="true" name="ShareBasedPaymentArrangementTrancheFourMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="duol_ShareBasedCompensationArrangementByShareBasedPaymentAwardSettlementPeriodAfterVesting" abstract="false" name="ShareBasedCompensationArrangementByShareBasedPaymentAwardSettlementPeriodAfterVesting" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:durationItemType"/>
  <xs:element id="duol_ShareBasedCompensationArrangementByShareBasedPaymentAwardOptionsRepurchasesInPeriod" abstract="false" name="ShareBasedCompensationArrangementByShareBasedPaymentAwardOptionsRepurchasesInPeriod" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:sharesItemType"/>
  <xs:element id="duol_EnglishTestMember" abstract="true" name="EnglishTestMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="duol_PreferredStockVotingRightsVotesPerShare" abstract="false" name="PreferredStockVotingRightsVotesPerShare" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:decimalItemType"/>
  <xs:element id="duol_ShareBasedPaymentArrangementEquityInstrumentsOtherThanOptionsTradingPricePeriod" abstract="false" name="ShareBasedPaymentArrangementEquityInstrumentsOtherThanOptionsTradingPricePeriod" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="xbrli:integerItemType"/>
  <xs:element id="duol_NonCashOperatingAndFinancingActivitiesAbstract" abstract="true" name="NonCashOperatingAndFinancingActivitiesAbstract" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:stringItemType"/>
  <xs:element id="duol_IncreaseDecreaseInCapitalizedContractCostsNet" abstract="false" name="IncreaseDecreaseInCapitalizedContractCostsNet" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="duol_FoundersMember" abstract="true" name="FoundersMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="duol_ShareBasedPaymentArrangementTrancheSixMember" abstract="true" name="ShareBasedPaymentArrangementTrancheSixMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="duol_StripeMember" abstract="true" name="StripeMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="duol_ShareBasedPaymentArrangementTrancheSevenMember" abstract="true" name="ShareBasedPaymentArrangementTrancheSevenMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="duol_RevenueFromContractWithCustomerLiabilityRollForward" abstract="true" name="RevenueFromContractWithCustomerLiabilityRollForward" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:stringItemType"/>
  <xs:element id="duol_ContractWithCustomerThresholdPeriodToTakeExamForBulkPurchase" abstract="false" name="ContractWithCustomerThresholdPeriodToTakeExamForBulkPurchase" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="xbrli:durationItemType"/>
  <xs:element id="duol_BusinessAndOrganizationTable" abstract="true" name="BusinessAndOrganizationTable" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrldt:hypercubeItem" type="xbrli:stringItemType"/>
  <xs:element id="duol_ContractWithCustomerLiabilityRevenueRecognizedExcludingOpeningBalance" abstract="false" name="ContractWithCustomerLiabilityRevenueRecognizedExcludingOpeningBalance" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="duol_NumberOfLanguages" abstract="false" name="NumberOfLanguages" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="xbrli:integerItemType"/>
  <xs:element id="duol_ContractWithCustomerThresholdToTakeExam" abstract="false" name="ContractWithCustomerThresholdToTakeExam" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="xbrli:durationItemType"/>
  <xs:element id="duol_NumberOfSourcesOfRevenue" abstract="false" name="NumberOfSourcesOfRevenue" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="xbrli:integerItemType"/>
  <xs:element id="duol_ShareBasedPaymentArrangementFoundersMember" abstract="true" name="ShareBasedPaymentArrangementFoundersMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="duol_ShareBasedCompensationArrangementsByShareBasedPaymentAwardOptionsRepurchasesInPeriodWeightedAverageExercisePrice" abstract="false" name="ShareBasedCompensationArrangementsByShareBasedPaymentAwardOptionsRepurchasesInPeriodWeightedAverageExercisePrice" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:perShareItemType"/>
  <xs:element id="duol_ShareBasedPaymentArrangementTrancheNineMember" abstract="true" name="ShareBasedPaymentArrangementTrancheNineMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="duol_ContractWithCustomerLiabilityAdditionsDuringThePeriod" abstract="false" name="ContractWithCustomerLiabilityAdditionsDuringThePeriod" nillable="true" xbrli:periodType="duration" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="duol_PaymentsForRepurchaseOfStockOptions" abstract="false" name="PaymentsForRepurchaseOfStockOptions" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="duol_EmployeeStockPurchasePlanMember" abstract="true" name="EmployeeStockPurchasePlanMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="duol_ScheduleOfAccruedLiabilitiesAndOtherCurrentLiabilitiesTableTextBlock" abstract="false" name="ScheduleOfAccruedLiabilitiesAndOtherCurrentLiabilitiesTableTextBlock" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:textBlockItemType"/>
  <xs:element id="duol_DefinedContributionPlanMatchingContributionPortionDomain" abstract="true" name="DefinedContributionPlanMatchingContributionPortionDomain" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="duol_StockholdersMember" abstract="true" name="StockholdersMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="duol_CapitalizedSoftwareExpendituresIncurredButNotYetPaid" abstract="false" name="CapitalizedSoftwareExpendituresIncurredButNotYetPaid" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="duol_AppleMember" abstract="true" name="AppleMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="duol_GoogleMember" abstract="true" name="GoogleMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="duol_IncentiveFromLandlordPaidButNotYetUtilized" abstract="false" name="IncentiveFromLandlordPaidButNotYetUtilized" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="duol_A2021IncentiveAwardPlanMember" abstract="true" name="A2021IncentiveAwardPlanMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="duol_ContractWithCustomerNumberOfUsersPerSubscription" abstract="false" name="ContractWithCustomerNumberOfUsersPerSubscription" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="xbrli:integerItemType"/>
  <xs:element id="duol_ShareBasedPaymentArrangementTrancheFiveMember" abstract="true" name="ShareBasedPaymentArrangementTrancheFiveMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="duol_ShareBasedCompensationArrangementByShareBasedPaymentAwardAwardRequisiteServicePeriodNumberOfTranches" abstract="false" name="ShareBasedCompensationArrangementByShareBasedPaymentAwardAwardRequisiteServicePeriodNumberOfTranches" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:integerItemType"/>
  <xs:element id="duol_ContractWithCustomerCertificationPeriodPriorToTestCompletion" abstract="false" name="ContractWithCustomerCertificationPeriodPriorToTestCompletion" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="xbrli:durationItemType"/>
  <xs:element id="duol_DuolingoMember" abstract="true" name="DuolingoMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="duol_MatchingContributionPortion1Member" abstract="true" name="MatchingContributionPortion1Member" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="duol_A2011EquityIncentivePlanMember" abstract="true" name="A2011EquityIncentivePlanMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="duol_MatchingContributionPortionTwoMember" abstract="true" name="MatchingContributionPortionTwoMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="duol_ShareBasedPaymentArrangementTrancheTenMember" abstract="true" name="ShareBasedPaymentArrangementTrancheTenMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="duol_ShareBasedPaymentArrangementTrancheEightMember" abstract="true" name="ShareBasedPaymentArrangementTrancheEightMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
  <xs:element id="duol_ShareBasedPaymentArrangementEquityInstrumentsOtherThanOptionsStockPriceHurdle" abstract="false" name="ShareBasedPaymentArrangementEquityInstrumentsOtherThanOptionsStockPriceHurdle" nillable="true" xbrli:periodType="instant" substitutionGroup="xbrli:item" type="dtr-types:perShareItemType"/>
  <xs:element id="duol_BusinessAndOrganizationLineItems" abstract="true" name="BusinessAndOrganizationLineItems" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="xbrli:stringItemType"/>
  <xs:element id="duol_DefinedContributionPlanMatchingContributionPortionAxis" abstract="true" name="DefinedContributionPlanMatchingContributionPortionAxis" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrldt:dimensionItem" type="xbrli:stringItemType"/>
  <xs:element id="duol_CloudComputingExpendituresIncurredButNotYetPaid" abstract="false" name="CloudComputingExpendituresIncurredButNotYetPaid" nillable="true" xbrli:periodType="duration" xbrli:balance="credit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="duol_StockRepurchasedDuringPeriodOptionsValue" abstract="false" name="StockRepurchasedDuringPeriodOptionsValue" nillable="true" xbrli:periodType="duration" xbrli:balance="debit" substitutionGroup="xbrli:item" type="xbrli:monetaryItemType"/>
  <xs:element id="duol_TrancheOneAndTrancheTwoMember" abstract="true" name="TrancheOneAndTrancheTwoMember" nillable="true" xbrli:periodType="duration" substitutionGroup="xbrli:item" type="dtr-types:domainItemType"/>
</xs:schema>
